Soapmaking
How do I handle lye safely?
Always add lye slowly to cold liquid, never the reverse. Wear full protective gear and never change a calculated lye amount.
The Big Book of Homemade Soap
Soapmaking
Cold and hot process soap, taught from the chemistry up: why lye must be respected, what superfat really does, how the gel phase changes a bar, and why curing is not optional.

Soap is what happens when oils meet an alkali. Sodium hydroxide turns fats into soap within 24–48 hours. What differs is where it finishes.
Cold process soap is blended to trace and saponifies in the mold. You choose whether it goes through gel, and it needs a full cure of at least 4–6 weeks. Hot process soap is cooked on low heat until it looks like waxy mashed potatoes. Superfat oils, delicate scents, milk and honey go in after the cook, and the bars need only 1–2 weeks of hardening.
Every oil changes the bar through its fatty acids. The book's balanced bars are roughly 28–30% coconut, 15–25% butters, 44–47% olive and 2–5% castor.
| Oil | What it brings | Watch out for |
|---|---|---|
| Coconut | Hardness, big bubbly lather, strong cleansing; fast trace | Drying at high levels unless superfatted |
| Olive | Mildness, conditioning, stable creamy lather | Slow trace; needs a long cure |
| Castor | Dense, creamy, stable lather (2–5%) | Sticky, soft bars above 5–7% |
| Shea, mango, cocoa | Hardness and creaminess | Soap warmer (43–46 °C) to avoid false trace |
| Calculator value | Book's range | What it predicts |
|---|---|---|
| Hardness | 29–54 (35–45) | How long the bar lasts |
| Cleansing | 12–22 | Oil-stripping power; above 22 may dry skin |
| Conditioning | 44–69 | Emollience |
| Bubbly lather | 14–46 | Big, fluffy bubbles |
| Creamy lather | 16–48 | Dense, stable lather |
| Iodine | < 60 ideal | Rancidity risk; above 70 is high |
The numbers are predictions, not laws. To change a bar, change the oils, never the lye.
Fresh soap heats itself. In gel phase it reaches 54–82 °C and turns semi-translucent, giving brighter colors and a harder bar. Insulate to encourage it; chill to prevent it. Milk soaps and layered designs are made without gel.
| Soap | Cure |
|---|---|
| High-coconut / utility bars | 2–3 weeks |
| Balanced cold process bar | 4–6 weeks |
| Hot process | 1–2 weeks |
| 60–80% soft oils | 6–12 weeks |
| No-gel, milk, high-butter bars | 8–10 weeks |
| 100% olive Castile | 6–12 months |

A multi-oil cold process bar with a rosemary-infused post-trace superfat and a spirulina swirl. About 500 g, 6% superfat.
| Ingredient | Amount | % of oils |
|---|---|---|
| Olive oil, extra virgin | 200 g | 46.51 |
| Coconut oil, refined | 130 g | 30.23 |
| Shea butter | 40 g | 9.30 |
| Mango butter | 30 g | 6.98 |
| Grape seed oil | 20 g | 4.65 |
| Castor oil | 10 g | 2.33 |
| Sodium hydroxide (NaOH) | 60.02 g | — |
| Distilled water | 116 g | 27 |
| Rosemary-infused olive oil (post-trace) | 10 g | 2.33 |
| Bergamot + lime essential oils | 5 g + 5 g | — |
| Spirulina powder (half the batch) | 1–1.5 tsp | — |
Key steps: bring lye and oils to a deliberately warm 43–46 °C so the butters stay fluid, blend to medium trace, add the macerate, then the essential oils. Split, color half with spirulina, swirl, spray with alcohol, gel in a warm switched-off oven, and cure 6–8 weeks.
Wear full protective gear and confirm the lye amount in a lye calculator for your exact oils. The book itself recommends SoapCalc.net.
Knowledge articles
Soapmaking
Always add lye slowly to cold liquid, never the reverse. Wear full protective gear and never change a calculated lye amount.
The Big Book of Homemade Soap
Soapmaking
It's the reaction between oils and lye that turns them into soap. As the book says: there is no soap without lye.
The Big Book of Homemade Soap
Soapmaking
Cold process soap saponifies in the mold and needs a full cure. Hot process soap is cooked until saponification is nearly complete, so it only needs 1–2 weeks to harden.
The Big Book of Homemade Soap
Soapmaking
It's a self-heating stage where fresh soap reaches 54–82 °C and turns semi-translucent, which speeds saponification.
The Big Book of Homemade Soap
Soapmaking
That's a partial gel: the center heated through gel phase but the edges didn't. It's cosmetic only; extend the cure.
The Big Book of Homemade Soap
Soapmaking
Most balanced cold process bars need 4–6 weeks; soft-oil bars need longer, and 100% olive Castile 6–12 months. Curing lets water evaporate, the pH settle and the bar harden.
The Big Book of Homemade Soap
Soapmaking
A deliberate excess of oil that the lye can't saponify. It stays in the bar as free oil, making it milder and ensuring no free lye remains.
The Big Book of Homemade Soap
Soapmaking
It's the book's signature technique: a standard superfat built into the lye calculation, plus a small amount of a precious oil added after trace.
The Big Book of Homemade Soap
Soapmaking
Trace is the point where the emulsified soap batter thickens. The book works with three stages: just emulsified, thin trace and medium trace.
The Big Book of Homemade Soap
Soapmaking
Certain ingredients and conditions speed up trace: some fragrance oils, citrus essential oils, sugars, milks, honey, juices, a water discount and high-coconut recipes.
The Big Book of Homemade Soap
Soapmaking
Usually a fragrance oil that isn't safe for cold process. Mixing fragrance and essential oils can do it too.
The Big Book of Homemade Soap
Soapmaking
Essential oils are natural volatile plant compounds; fragrance oils are lab-made blends with a stronger, more stable scent. Both work, but fragrance oils must be cold-process safe for soap.
The Big Book of Homemade Soap · The Big Book of Sweet Dessert Candles
Soapmaking
The books set clear limits but don't describe what happens above them, so stay within the stated ranges.
The Big Book of Homemade Soap · The Big Book of Sweet Dessert Candles
Soapmaking
Vanillin in the fragrance oil oxidizes in alkaline soap and turns it from beige to deep brown. A vanilla stabilizer slows or prevents it.
The Big Book of Homemade Soap
Soapmaking
That's soda ash: a harmless, powdery film of sodium carbonate formed by carbon dioxide in the air. Spray fresh soap with alcohol to prevent it.
The Big Book of Homemade Soap
Soapmaking
Each oil's fatty acids shape the bar: coconut brings hardness and big lather, olive brings mildness and conditioning, castor stabilizes lather, and butters add hardness and creaminess.
The Big Book of Homemade Soap
Soapmaking
They're predictions calculated from fatty-acid profiles. Use them as a guide, not as laws.
The Big Book of Homemade Soap
Soapmaking
Using less water than the usual 33–38% of oil weight. The book's recipes mostly use 26–27%.
The Big Book of Homemade Soap
Soapmaking
Yes. Milk makes a very mild, creamy bar, but its sugars and proteins scorch easily, so it must be kept cold and soaped without gel.
The Big Book of Homemade Soap
Soapmaking
Both boost lather, but they heat the batter and speed up trace, so add them carefully and keep things cool.
The Big Book of Homemade Soap
Soapmaking
With clays, activated charcoal, spirulina, spices and macerated oils, always pre-dispersed first to avoid specks.
The Big Book of Homemade Soap
Soapmaking
Blend only to 'just emulsified', divide straight away, finish each layer separately, and keep the soap cool so it doesn't gel.
The Big Book of Homemade Soap
Soapmaking
It was overcooked and lost moisture. Knead in warm water, milk or aloe juice a teaspoon at a time until it's like putty.
The Big Book of Homemade Soap
Soapmaking
Olive oil is mostly oleic acid, which saponifies slowly: slow trace, a soft young bar, and a 6–12 month cure.
The Big Book of Homemade Soap
Soapmaking
It can be. Coconut oil cleanses strongly, so as a skin bar it needs a high superfat of 15–20%. At 0–3% it's a household bar.
The Big Book of Homemade Soap
Soapmaking
Concentrated lye would react violently with acidic juice and destroy a hydrosol's compounds. In the oils they disperse and are buffered.
The Big Book of Homemade Soap
Go deeper
Seven theory chapters, ten recipes from Castile to hot process jasmine, and a troubleshooting FAQ for every recipe.
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